A correct pre-plate
preparation is essential to obtain the maximum adhesion between the
material to be plated and electrodeposited chromium. There are three
general areas of consideration for the preparation of the base
material: The Base material itself, cleaning and activation.
A plater must determine the
type of base material and finish prior to plate. Chromium plating
magnifies and exaggerates imperfections on the surface of the base
material.
To obtain a smooth chromium
plated surface, it is necessary to start with a smooth and defect free
surface. This smooth, defect free base material must also be clean and
free of surface contamination. The source of contamination can come
from a smeared layer of the base material that was not removed in the
metal forming operation, embedded shot from a shot peen process or
layers of films such as grease, oil or dirt. The cleaning of the base
material varies with the material at hand, i.e., Cast iron, stainless,
inconel or carbon steel and their subsequent finish call outs.
Many hard chrome plated
materials are later mechanically ground to a finish dimension. In this
case, materials are degreased, alkalined cleaned if required and
blasted with aluminum oxide to specification prior to plate. After
this cleaning, it is essential that the parts be moved through any
masking operation and into the plating solution within a specific time
so that oxidation is not permitted to occur.
Once material has been
identified as to its composition and cleaned properly to
specification, it is introduced into the plating solution or pre-plate
etching solution for activation. The pre-plate etching procedure
varies depending on the base material. Many steels are anodically or
reversed etched in a chrome tank prior to plate. This microscopic
etching of the base material is essential for proper adhesion of the
chromium. High heat treated steels are sometimes required to be etched
in a special bath consisting of sulfuric and hydrofluoric acids prior
to introduction into the chromium solution for plating. Stainless
steels and high nickel alloys show much greater adhesion with chromium
if cathodically activated in a bath of low concentrated sulfuric acid
prior to plate. The amount of time for these etchings or activation
operations vary as to the material and specification. As you may
suspect, many of these solutions have the ability of over-etching so
care must be taken in their utilization.
Chromium and its substrate do not have an absolute bond. the bond can
be broken through abusive use, improper grinding procedures that
produce excessive heat or a corrosive chemical that is not compatible
with the chromium deposit.
We hope this summary of
pre-plate preparation gives you some insight into how essential a lean
and properly prepared surface is when creating a long lasting and
durable bond between a chromium deposit and a substrate.
In our next newsletter, we
will give you a look at one of the most misunderstood and overlooked
areas of manufacturing when using heat treated materials.